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Chemosphere


Title:Photocatalytic oxidation of gaseous chlorinated organics over titanium dioxide
Author(s):Hager S; Bauer R; Kudielka G;
Address:"Institute of Physical Chemistry, Vienna University of Technology, Austria"
Journal Title:Chemosphere
Year:2000
Volume:41
Issue:8
Page Number:1219 - 1225
DOI: 10.1016/s0045-6535(99)00558-5
ISSN/ISBN:0045-6535 (Print) 0045-6535 (Linking)
Abstract:"The photocatalytic oxidation of high levels of volatile chlorinated organic compounds in gas phase has been studied using a specially designed photoreactor. The influence of light intensity, initial water vapour concentration, temperature, inlet contaminant concentration and flow rate on destruction efficiency has been investigated. The performance of the titanium catalyst was strongly affected by the presence of water in the air stream. Experiments have been most successfully conducted at room temperature, low initial contaminant concentrations, low flow rates and high light intensities. Several by-products have been detected performing photocatalytic degradation of trichloroethylene (TCE) and tetrachloroethylene (PCE). No catalyst deactivation was observed"
Keywords:Catalysis Coloring Agents/*metabolism Light Oxidation-Reduction Photochemistry Solvents/*metabolism Temperature Tetrachloroethylene/*metabolism Titanium/*metabolism Trichloroethylene/*metabolism Volatilization;
Notes:"MedlineHager, S Bauer, R Kudielka, G eng Research Support, Non-U.S. Gov't England 2000/07/20 Chemosphere. 2000 Oct; 41(8):1219-25. doi: 10.1016/s0045-6535(99)00558-5"

 
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