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Carbohydr Res

Title:		Pd(II)/PhI(OAc)(2) promoted direct cross coupling of glucals with aromatic acids
Author(s):		Begum Z; Shankar G; Sirisha K; Reddy BVS;
Address:		"Centre for Semiochemicals, India. Centre for Nuclear Magnetic Resonance, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500 007, India. Centre for Semiochemicals, India. Electronic address: basireddy@iict.res.in"
Journal Title:		Carbohydr Res
Year:		2018
Volume:		20180312
Issue:
Page Number:		1 - 3
DOI:		10.1016/j.carres.2018.03.002
ISSN/ISBN:		1873-426X (Electronic) 0008-6215 (Linking)
Abstract:		A highly efficient oxidative C2-aroyloxylation of D-glucal with aromatic carboxylic acids has been achieved for the first time using 5?ª+mol% Pd(OAc)(2) and 1 equiv of PhI(OAc)(2) to produce C2-aroyloxyglycals in good yields. The use of excess of PhI(OAc)(2) (2 equiv) provides C2-acyloxyglycal exclusively
Keywords:		"Acetates/*chemistry Amino Acids, Aromatic/*chemistry Carboxylic Acids/*chemistry Iodobenzenes/*chemistry Molecular Structure Palladium/*chemistry C-H activation C2-aroyloxyglycals D-glucal Hypervalent iodonium reagent Transition metal catalysis;"
Notes:		"MedlineBegum, Zubeda Shankar, G Sirisha, K Reddy, B V Subba eng Netherlands 2018/03/20 Carbohydr Res. 2018 May 22; 461:1-3. doi: 10.1016/j.carres.2018.03.002. Epub 2018 Mar 12"