| Title: | Advanced mono- and multi-dimensional gas chromatography-mass spectrometry techniques for oxygen-containing compound characterization in biomass and biofuel samples |
| Author(s): | Beccaria M; Siqueira ALM; Maniquet A; Giusti P; Piparo M; Stefanuto PH; Focant JF; |
| Address: | "Organic and Biological Analytical Chemistry Group, MolSys Research Unit, University of Liege, Liege, Belgium. TOTAL Marketing Services, Research Center, Solaize, France. International Joint Laboratory - iC2MC: Complex Matrices Molecular Characterization, TRTG, Harfleur, France. TOTAL Refining and Chemicals, Total Research and Technologies Gonfreville, Harfleur, France" |
| ISSN/ISBN: | 1615-9314 (Electronic) 1615-9306 (Linking) |
| Abstract: | "A wide variety of biomass, from triglycerides to lignocellulosic-based feedstock, are among promising candidates to possibly fulfill requirements as a substitute for crude oils as primary sources of chemical energy feedstock. During the feedstock processing carried out to increase the H:C ratio of the products, heteroatom-containing compounds can promote corrosion, thus limiting and/or deactivating catalytic processes needed to transform the biomass into fuel. The use of advanced gas chromatography techniques, in particular multi-dimensional gas chromatography, both heart-cutting and comprehensive coupled to mass spectrometry, has been widely exploited in the field of petroleomics over the past 30 years and has also been successfully applied to the characterization of volatile and semi-volatile compounds during the processing of biomass feedstock. This review intends to describe advanced gas chromatography-mass spectrometry-based techniques, mainly focusing in the period 2011-early 2020. Particular emphasis has been devoted to the multi-dimensional gas chromatography-mass spectrometry techniques, for the isolation and characterization of the oxygen-containing compounds in biomass feedstock. Within this context, the most recent advances to sample preparation, derivatization, as well as gas chromatography instrumentation, mass spectrometry ionization, identification, and data handling in the biomass industry, are described" |
| Keywords: | Biofuels/*analysis Biomass Gas Chromatography-Mass Spectrometry Oxygen/*analysis Gc-ms analytical pyrolysis biofuels oxygen compounds; |
| Notes: | "MedlineBeccaria, Marco Siqueira, Anna Luiza Mendes Maniquet, Adrien Giusti, Pierre Piparo, Marco Stefanuto, Pierre-Hugues Focant, Jean-Francois eng Review Germany 2020/11/14 J Sep Sci. 2021 Jan; 44(1):115-134. doi: 10.1002/jssc.202000907. Epub 2020 Dec 9" |
