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Sci Total Environ


Title:"Compositions, sources and health risks of ambient volatile organic compounds (VOCs) at a petrochemical industrial park along the Yangtze River"
Author(s):Zheng H; Kong S; Yan Y; Chen N; Yao L; Liu X; Wu F; Cheng Y; Niu Z; Zheng S; Zeng X; Yan Q; Wu J; Zheng M; Liu D; Zhao D; Qi S;
Address:"Department of Atmospheric Science, School of Environmental Sciences, China University of Geosciences, Wuhan 430074, China; Department of Environmental Science and Technology, School of Environmental Sciences, China University of Geosciences, Wuhan 430074, China. Department of Atmospheric Science, School of Environmental Sciences, China University of Geosciences, Wuhan 430074, China. Electronic address: kongshaofei@cug.edu.cn. Department of Atmospheric Science, School of Environmental Sciences, China University of Geosciences, Wuhan 430074, China. Hubei Environmental Monitoring Centre, Wuhan 430072, China. Department of Environmental Science and Technology, School of Environmental Sciences, China University of Geosciences, Wuhan 430074, China. Department of Environmental Science and Technology, School of Environmental Sciences, China University of Geosciences, Wuhan 430074, China; Hubei Environmental Monitoring Centre, Wuhan 430072, China. Department of Atmospheric Sciences, School of Earth Sciences, Zhejiang University, Hangzhou 310058, China. Beijing Weather Modification Office, Beijing 100089, China"
Journal Title:Sci Total Environ
Year:2020
Volume:20191113
Issue:
Page Number:135505 -
DOI: 10.1016/j.scitotenv.2019.135505
ISSN/ISBN:1879-1026 (Electronic) 0048-9697 (Linking)
Abstract:"Petrochemical industry (PI) is an important emission sector of anthropogenic volatile organic compounds (VOCs). The health impacts of VOCs from PI have caused a wide attention by both scientists and publics. In this study, compositions, sources and health risks of VOCs at a typical petrochemical industrial park along the middle reach of Yangtze River were studied. The total VOC concentrations were in the range of 5.59 to 541 ppbv with a mean value of 54.8 ppbv. Alkanes (41.4?ª++/-?ª+15.7%) were the predominant group, followed by alkenes (19.9?ª++/-?ª+18.3%), OVOCs (14.7?ª++/-?ª+9.26%), halo hydrocarbon (11.2?ª++/-?ª+6.42%), aromatics (8.17?ª++/-?ª+5.08%), and acetylene (4.54?ª++/-?ª+2.80%). Compound-specific health risk results showed that acrolein and 1,3-butadiene had the highest non-carcinogenic risk (expressed by hazard ratio, HR: 22.8) and carcinogenic risk (expressed by lifetime cancer risk, LCR: 6.7?ª+x?ª+10(-3)), respectively. Positive matrix factorization (PMF) model identified four VOC sources including fuel evaporation, industrial sources, ethylene industry and regional background with the average contributions of 35.6%, 12.0%, 26.5% and 25.9%, respectively. The receptor-originated approach combining the PMF model and conventional methods (HR and LCR) was used to assess the source-specific health risks. The non-cancer risks of four VOC sources were above safe level with regional background contributing most (38.3% or 4.91) to HR. The cancer risks of the four sources were below the tolerable level (<10(-4)) and regional background also contributed most, with relative contribution of 58.4% (or 10(-)(4.22)) to LCR. Our results are conductive to the formulation of countermeasures to reduce human exposure to ambient VOCs at petrochemical industrial parks in China"
Keywords:Air Pollutants/*analysis China *Environmental Monitoring Industry Volatile Organic Compounds/*analysis Health risk assessment Monte-Carlo simulation Petrochemical industrial park Source apportionment Volatile organic compounds;
Notes:"MedlineZheng, Huang Kong, Shaofei Yan, Yingying Chen, Nan Yao, Liquan Liu, Xi Wu, Fangqi Cheng, Yi Niu, Zhenzhen Zheng, Shurui Zeng, Xin Yan, Qin Wu, Jian Zheng, Mingming Liu, Dantong Zhao, Delong Qi, Shihua eng Netherlands 2019/11/25 Sci Total Environ. 2020 Feb 10; 703:135505. doi: 10.1016/j.scitotenv.2019.135505. Epub 2019 Nov 13"

 
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