| Title: | Comparison of extraction techniques for gas chromatographic determination of volatile carbonyl compounds in alcohols |
| Author(s): | Wardencki W; Orlita J; Namiesnik J; |
| Address: | "Department of Analytical Chemistry, Chemical Faculty, Technical University of Gdansk, Poland. wawar@chem.pg.gda.pl" |
| ISSN/ISBN: | 0937-0633 (Print) 0937-0633 (Linking) |
| Abstract: | "Two extraction procedures, i.e. conventional liquid-liquid extraction (LLE) and liquid solid-phase microextraction (SPME) for extraction of the oximes formed after derivatization of carbonyl compounds with o-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine (PFBHA) in alcoholic solutions have been compared. The limit of detection for LLE followed by GC-ECD determination of C1-C6 was in the range of 0.23-3.3 microg/L, whereas for liquid SPME 0.005-0.33 microg/L. Both methods elaborated can be applied to the determination of carbonyl compounds present in spirits and alcoholic beverages" |
| Keywords: | "Alcoholic Beverages/*analysis Alcohols/*analysis Carcinogens/analysis Chromatography, Gas/methods Indicators and Reagents Mutagens/analysis Organic Chemicals/*analysis;" |
| Notes: | "MedlineWardencki, W Orlita, J Namiesnik, J eng Comparative Study Research Support, Non-U.S. Gov't Germany 2001/05/24 Fresenius J Anal Chem. 2001 Apr; 369(7-8):661-5. doi: 10.1007/s002160100738" |
