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« Previous AbstractHigh dietary total antioxidant capacity is associated with a reduced risk of hypertension in French women    Next AbstractAnalysis of a GC/MS thermal desorption system with simultaneous sniffing for determination of off-odor compounds and VOCs in fumes formed during extrusion coating of low-density polyethylene »

J Chromatogr A


Title:Analysis of odour and taste problems in high-density polyethene
Author(s):Villberg K; Veijanen A; Gustafsson I; Wickstrom K;
Address:"University of Jyvaskyla, Department of Chemistry, Finland"
Journal Title:J Chromatogr A
Year:1997
Volume:791
Issue:1-Feb
Page Number:213 - 219
DOI: 10.1016/s0021-9673(97)00769-3
ISSN/ISBN:0021-9673 (Print) 0021-9673 (Linking)
Abstract:"The compounds that cause off-flavours in plastics, have been recognized mainly as carbonyl compounds (aldehydes, ketones and esters). They occur in low concentrations, and due to their low-threshold odour concentrations, their typical odours were identified. Most of these off-flavour compounds are volatile. Chemical analysis of smelling compounds requires a very sensitive method with a high-resolution capability. The analysis of volatile organic compounds (VOCs) in high density polyethene (HD-PE) granules and waters in which the granules have been shaken for 4 h, were carried out by gas chromatography-mass spectrometry-sniffing system (GC-MS-SNIFF) and by gas chromatography-fourier transform infrared spectroscopy-sniffing system (GC-FTIR-SNIFF). A purge-and-trap technique was used to introduce the VOCs from samples into the gas chromatograph. Leaching waters of HD-PE granules were also evaluated by panel. This panel agreed upon six descriptive attributes for odour: sweet, chemical, stale, dusty, foul and floor-cloth. The attributes for taste were: sweet, metallic, stony, pungent, dusty, plastic, foul, stink bug and candle grease"
Keywords:"Chromatography, Gas/*methods Mass Spectrometry/*methods Odorants/*analysis Polyethylenes/*chemistry Reproducibility of Results Sensitivity and Specificity *Taste Water Supply/*analysis/standards;"
Notes:"MedlineVillberg, K Veijanen, A Gustafsson, I Wickstrom, K eng Comparative Study Research Support, Non-U.S. Gov't Netherlands 1998/02/17 J Chromatogr A. 1997 Dec 12; 791(1-2):213-9. doi: 10.1016/s0021-9673(97)00769-3"

 
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