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Sensors (Basel)

Title:		"Non-Contact, Continuous Sampling of Porous Surfaces for the Detection of Particulate and Adsorbed Organic Contaminations by Low-Temperature Plasma Coupled to Ion Mobility Spectrometer"
Author(s):		Ron I; Sharabi H; Zaltsman A; Leibman A; Hotoveli M; Pevzner A; Kendler S;
Address:		"Department of Physical Chemistry, Israel Institute for Biological Research, Ness Ziona 74100, Israel. Department of Environmental, Water and Agricultural Engineering, Faculty of Civil & Environmental Engineering, Technion-Israel Institute of Technology, Haifa 32000, Israel. Department of Environmental Physics, Israel Institute for Biological Research, Ness Ziona 74100, Israel"
Journal Title:		Sensors (Basel)
Year:		2023
Volume:		20230217
Issue:		4
Page Number:		-
DOI:		10.3390/s23042253
ISSN/ISBN:		1424-8220 (Electronic) 1424-8220 (Linking)
Abstract:		"Chemical analysis of hazardous surface contaminations, such as hazardous substances, explosives or illicit drugs, is an essential task in security, environmental and safety applications. This task is mostly based on the collection of particles with swabs, followed by thermal desorption into a vapor analyzer, usually a detector based on ion mobility spectrometry (IMS). While this methodology is well established for several civil applications, such as border control, it is still not efficient enough for various conditions, as in sampling rough and porous surfaces. Additionally, the process of thermal desorption is energetically inefficient, requires bulky hardware and introduces device contamination memory effects. Low-temperature plasma (LTP) has been demonstrated as an ionization and desorption source for sample preparation-free analysis, mostly at the inlet of a mass spectrometer analyzer, and in rare cases in conjunction with an ion mobility spectrometer. Herein, we demonstrate, for the first time, the operation of a simple, low cost, home-built LTP apparatus for desorbing non-volatile analytes from various porous surfaces into the inlet of a handheld IMS vapor analyzer. We show ion mobility spectra that originate from operating the LTP jet on porous surfaces such as asphalt and shoes, contaminated with model amine-containing organic compounds. The spectra are in good correlation with spectra measured for thermally desorbed species. We verify through LC-MS analysis of the collected vapors that the sampled species are not fragmented, and can thus be identified by commercial IMS detectors"
Keywords:		ion mobility spectrometry on-site analysis sampling;
Notes:		"PubMed-not-MEDLINERon, Izhar Sharabi, Hagay Zaltsman, Amalia Leibman, Amir Hotoveli, Mordi Pevzner, Alexander Kendler, Shai eng Switzerland 2023/03/01 Sensors (Basel). 2023 Feb 17; 23(4):2253. doi: 10.3390/s23042253"