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Int J Food Sci Nutr

Title:		Assessment of the oxidative stability of conventional and high-oleic sunflower oil by means of solid-phase microextraction-gas chromatography
Author(s):		Petersen KD; Kleeberg KK; Jahreis G; Fritsche J;
Address:		"Hochschule fur Angewandte Wissenschaften, Lohbrugger Kirchstrasse 65, D-21033 Hamburg, Germany"
Journal Title:		Int J Food Sci Nutr
Year:		2012
Volume:		20110819
Issue:		2
Page Number:		160 - 169
DOI:		10.3109/09637486.2011.609158
ISSN/ISBN:		1465-3478 (Electronic) 0963-7486 (Linking)
Abstract:		"Headspace-solid-phase microextraction-gas chromatography (HS-SPME-GC) was used to identify in total 74 volatile lipid oxidation compounds altogether in thermally stressed conventional and high-oleic sunflower (HOSF) oil samples (in accelerated storage conditions for 14 days at 80 degrees C). Out of the volatile compounds identified, six volatile compounds were selected as marker compounds for the assessment of lipid oxidation of sunflower (SF) and HOSF oils due to their low odour threshold values and fatty-rancid odour impression. Additionally, other oxidation parameters such as fatty acid composition, peroxide value (PV), anisidine value and tocopherol and tocotrienol composition were determined. Multivariate statistical methods (principal component analysis and agglomerative hierarchical cluster analysis) were applied to identify sensitive oxidation marker compounds. Preliminary results revealed that hexanal, E-2-heptenal, E-2-decenal and E,E-2,4-nonadienal were the most suitable in differentiating HOSF and SF oil varieties from each other and SF samples with differing oxidative properties. Differentiation of SF samples according to their volatile compound composition was done in accordance with the results from the well-known oil quality parameters (e.g. PV or fatty acid composition). In conclusion, the combination of volatile compound analysis with HS-SPME-GC and multivariate statistical methods provides a sensitive tool in differentiating conventional SF and HOSF oils by means of volatile lipid oxidation marker compounds"
Keywords:		"Chromatography, Gas/*methods Cluster Analysis Dietary Fats/metabolism Fatty Acids/analysis/metabolism Helianthus/*chemistry Hot Temperature *Lipid Peroxidation Multivariate Analysis Odorants Oleic Acid/*metabolism Oxidation-Reduction Plant Oils/*metabolis;"
Notes:		"MedlinePetersen, Katharina Domitila Kleeberg, Kim Karen Jahreis, Gerhard Fritsche, Jan eng Research Support, Non-U.S. Gov't Validation Study England 2011/08/23 Int J Food Sci Nutr. 2012 Mar; 63(2):160-9. doi: 10.3109/09637486.2011.609158. Epub 2011 Aug 19"