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Nanoscale


Title:Hierarchical nanostructured WO3-SnO2 for selective sensing of volatile organic compounds
Author(s):Nayak AK; Ghosh R; Santra S; Guha PK; Pradhan D;
Address:"Materials Science Centre, Indian Institute of Technology, Kharagpur, W. B. 721 302, India. deb@matsc.iitkgp.ernet.in"
Journal Title:Nanoscale
Year:2015
Volume:20150702
Issue:29
Page Number:12460 - 12473
DOI: 10.1039/c5nr02571k
ISSN/ISBN:2040-3372 (Electronic) 2040-3364 (Linking)
Abstract:"It remains a challenge to find a suitable gas sensing material that shows a high response and shows selectivity towards various gases simultaneously. Here, we report a mixed metal oxide WO3-SnO2 nanostructured material synthesized in situ by a simple, single-step, one-pot hydrothermal method at 200 degrees C in 12 h, and demonstrate its superior sensing behavior towards volatile organic compounds (VOCs) such as ammonia, ethanol and acetone. SnO2 nanoparticles with controlled size and density were uniformly grown on WO3 nanoplates by varying the tin precursor. The density of the SnO2 nanoparticles on the WO3 nanoplates plays a crucial role in the VOC selectivity. The responses of the present mixed metal oxides are found to be much higher than the previously reported results based on single/mixed oxides and noble metal-doped oxides. In addition, the VOC selectivity is found to be highly temperature-dependent, with optimum performance obtained at 200 degrees C, 300 degrees C and 350 degrees C for ammonia, ethanol and acetone, respectively. The present results on the cost-effective noble metal-free WO3-SnO2 sensor could find potential application in human breath analysis by non-invasive detection"
Keywords:
Notes:"PubMed-not-MEDLINENayak, Arpan Kumar Ghosh, Ruma Santra, Sumita Guha, Prasanta Kumar Pradhan, Debabrata eng Research Support, Non-U.S. Gov't England 2015/07/03 Nanoscale. 2015 Aug 7; 7(29):12460-73. doi: 10.1039/c5nr02571k. Epub 2015 Jul 2"

 
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