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J Agric Food Chem


Title:"Key Odorants from the American Matsutake, Tricholoma magnivelare"
Author(s):Murray AF; Moore AJ; Munafo JP;
Address:"Department of Food Science, University of Tennessee, Knoxville, Tennessee 37996, United States"
Journal Title:J Agric Food Chem
Year:2020
Volume:20200825
Issue:36
Page Number:9768 - 9775
DOI: 10.1021/acs.jafc.0c03372
ISSN/ISBN:1520-5118 (Electronic) 0021-8561 (Linking)
Abstract:"The American Matsutake, Tricholoma magnivelare (Peck) Redhead, is an edible wild mushroom with a distinctive aroma described as mushroom and spice with subtle floral and citrus nuances. In this study, a total of 36 odorants were identified from T. magnivelare using solvent-assisted flavor evaporation and aroma extract dilution analysis. Stable isotope dilution assays were performed to quantitate 14 odorants with flavor dilution factors >/=64. Odorants with high odor activity values (OAVs) included 1-octen-3-one (OAV 2125), linalool (OAV 650), (2E,4E)-nona-2,4-dienal (OAV 304), and 1-octen-3-ol (OAV 206). An odor simulation model matched the odor profile of the fresh mushroom. Omission studies showed that linalool, hexanal, (2E,4E)-nona-2,4-dienal, methyl (E)-3-phenylprop-2-enoate, and 1-octen-3-one or 1-octen-3-ol were essential to the aroma of T. magnivelare. Chiral chromatography showed that alpha-pinene was a scalemic mixture of 34% (R)-(+) to 66% (S)-(-), while 1-octen-3-ol was present as 95% (R)-(-) to 5% (S)-(+), and linalool was 96% (R)-(-) to 4% (S)-(+). These results establish the base for future investigations into the aroma chemistry of other members of the genus Tricholoma"
Keywords:Agaricales/*chemistry Aldehydes/chemistry Flavoring Agents/*chemistry Gas Chromatography-Mass Spectrometry Ketones/chemistry Monoterpenes/chemistry Odorants/*analysis United States American Matsutake Tricholoma magnivelare aroma extract dilution analysis;
Notes:"MedlineMurray, Anne F Moore, Andrew J Munafo, John P Jr eng 2020/08/26 J Agric Food Chem. 2020 Sep 9; 68(36):9768-9775. doi: 10.1021/acs.jafc.0c03372. Epub 2020 Aug 25"

 
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