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Int J Hyg Environ Health


Title:Occurrence of brominated disinfection byproducts in the air and water of chlorinated seawater swimming pools
Author(s):Manasfi T; Temime-Roussel B; Coulomb B; Vassalo L; Boudenne JL;
Address:"Aix Marseille Univ, CNRS, LCE, Marseille, France. Electronic address: tarek.manasfi@univ-amu.fr. Aix Marseille Univ, CNRS, LCE, Marseille, France. Electronic address: brice.temime-roussel@univ-amu.fr. Aix Marseille Univ, CNRS, LCE, Marseille, France. Electronic address: bruno.coulomb@univ-amu.fr. Aix Marseille Univ, CNRS, LCE, Marseille, France. Electronic address: laurent.vassalo@univ-amu.fr. Aix Marseille Univ, CNRS, LCE, Marseille, France. Electronic address: jean-luc.boudenne@univ-amu.fr"
Journal Title:Int J Hyg Environ Health
Year:2017
Volume:20170205
Issue:3
Page Number:583 - 590
DOI: 10.1016/j.ijheh.2017.01.008
ISSN/ISBN:1618-131X (Electronic) 1438-4639 (Linking)
Abstract:"An undesirable consequence of disinfection is the formation of chemical contaminants known as disinfection byproducts (DBPs). Chronic exposure to DBPs has been linked to adverse health effects. The occurrence of DBPs in chlorinated pools filled with seawater (such as thalassotherapy pools and pools in spas) has received little attention so far. The present study evaluated the speciation and levels of disinfection byproducts in indoor swimming pools filled with seawater and treated with chlorine. Water and air samples were collected from three indoor swimming pools located in Southern France. Several classes of DBPs including trihalomethanes, haloacetic acids, haloacetonitriles, and trihaloacetaldehydes were analyzed in water. Halogenated volatile organic compounds were analyzed in air. Extractable organic halides (EOX) contents were determined using combustion/micro-coulometry system. The speciation of DBPs identified in the three pools was predominantly brominated. The mean (arithmetic) concentration of bromoform, dibromoacetic acid, tribromoacetic acid, dibromoacetonitrile and bromal hydrate in the three pools was 79.2, 72.9, 59.9, 26.9 and 10.0mug/L, respectively. By weight, HAAs represented the most abundant chemical class followed by THMs. In air, bromoform was the most abundant THM occurring at a mean concentration of 133.2mug/m(3) in the three pools. The mean EOX level was 706mugCl(-)/L for the three pools. In average, the quantified DBPs accounted for only 14% of EOX, thus 86% of EOX remained unknown. Further research is warranted to identify the unknown DBPs"
Keywords:"Acetates/analysis Acetonitriles/analysis Air Pollutants/*analysis Chlorine Disinfectants *Disinfection Environmental Monitoring *Halogenation Hydrocarbons, Halogenated/analysis *Swimming Pools Water Pollutants, Chemical/*analysis Brominated compounds Chlo;"
Notes:"MedlineManasfi, Tarek Temime-Roussel, Brice Coulomb, Bruno Vassalo, Laurent Boudenne, Jean-Luc eng Germany 2017/02/16 Int J Hyg Environ Health. 2017 May; 220(3):583-590. doi: 10.1016/j.ijheh.2017.01.008. Epub 2017 Feb 5"

 
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