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J Hazard Mater

Title:		Insights into the high performance of Mn-Co oxides derived from metal-organic frameworks for total toluene oxidation
Author(s):		Luo Y; Zheng Y; Zuo J; Feng X; Wang X; Zhang T; Zhang K; Jiang L;
Address:		"Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian Normal University, Fuzhou 350007, PR China. National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, PR China. Electronic address: xywang2017@fzu.edu.cn. National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, PR China. National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou, PR China. Electronic address: jll@fzu.edu.cn"
Journal Title:		J Hazard Mater
Year:		2018
Volume:		20180131
Issue:
Page Number:		119 - 127
DOI:		10.1016/j.jhazmat.2018.01.053
ISSN/ISBN:		1873-3336 (Electronic) 0304-3894 (Linking)
Abstract:		"Mn-Co mixed metal oxide is considered as efficient catalyst for the total oxidation of volatile organic compounds. In this study, nanocube-like metal-organic frameworks (Mn(3)[Co(CN)(6)](2).nH(2)O) are adopted as the precursor to generate Mn-Co oxides with different Mn/Co molar ratios, which affect little on phase structure and textural properties. The obtained MOF-Mn1Co1 with uniform metal dispersion is rich in high valence of surface Mn(4+) and Co(3+) species, leading to high low-temperature catalytic activity of total toluene oxidation. The results of toluene-TPD followed by TPO and toluene-TPSR match well with the catalytic performances of MOF-Mn1Co1, MOF-Mn1Co2, and MOF-Mn2Co1, and in situ FITR proves that the benzoate route exists over MOF-Mn1Co1. It is found that a moderate ratio of Mn/Co (1:1) favors good low-temperature reducibility and high O(ads)/O(latt), resulting in superior oxidation performance. However, the stability in the existence of water for MOF-Mn1Co1 is not satisfied, which should be overcome in the future"
Keywords:		Catalytic oxidation Metal-organic frameworks Mn-Co oxides Nanocubes Toluene;
Notes:		"PubMed-not-MEDLINELuo, Yongjin Zheng, Yingbin Zuo, Jiachang Feng, Xiaoshan Wang, Xiuyun Zhang, Tianhua Zhang, Kai Jiang, Lilong eng Netherlands 2018/02/08 J Hazard Mater. 2018 May 5; 349:119-127. doi: 10.1016/j.jhazmat.2018.01.053. Epub 2018 Jan 31"