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Environ Toxicol Chem

Title:		Model predictions of toxaphene degradation in the atmosphere over North America
Author(s):		Li R; Jin J;
Address:		"Department of Plants, Soils, and Climate, Utah State University, Logan, Utah, USA"
Journal Title:		Environ Toxicol Chem
Year:		2013
Volume:		20131010
Issue:		12
Page Number:		2663 - 2671
DOI:		10.1002/etc.2344
ISSN/ISBN:		1552-8618 (Electronic) 0730-7268 (Linking)
Abstract:		"Technical toxaphene, a broad-spectrum pesticide mixture, degrades in the environment, resulting in potential changes in toxicity. The present study uses a multimedia model that the authors developed to estimate toxaphene degradation in the atmosphere over North America. The predicted degradation has strong spatial and temporal variability determined by processes such as emission and transport of technical toxaphene, as well as the complex interactions among many species (e.g., toxaphene, hydroxyl [OH] radicals, and ozone). More toxaphene is degraded in warmer months due to higher concentrations of technical toxaphene (primarily due to higher technical toxaphene emissions in the southeastern United States and transport to other regions) and OH radicals. In the model, OH radicals are created primarily through the reactions of water vapor with the excited oxygen atom, O((1)D), generated by the photolysis of ozone, which is produced primarily by reactions of volatile organic compounds and nitrogen oxides (NOx) in the presence of sunlight. The higher OH concentrations in warmer months are primarily the result of higher solar radiation and ozone concentrations. The spatial distribution of degradation depends on the distribution of technical toxaphene soil residues as well as atmospheric transport and chemistry; significant chemical degradation occurs in the southeastern United States where soils are most heavily contaminated by past applications of toxaphene"
Keywords:		"Atmosphere/*chemistry Models, Chemical Nitrogen Oxides/chemistry North America Pesticide Residues/chemistry Pesticides/*chemistry Photolysis Reactive Oxygen Species/chemistry Soil Pollutants/*chemistry Solar Energy Sunlight Toxaphene/*chemistry Chemical t;"
Notes:		"MedlineLi, R Jin, J eng Research Support, U.S. Gov't, Non-P.H.S. 2013/08/14 Environ Toxicol Chem. 2013 Dec; 32(12):2663-71. doi: 10.1002/etc.2344. Epub 2013 Oct 10"