| Title: | Comparison of methods employing gas chromatography retention data to determine vapour pressures at 298 K |
| Author(s): | Koutek B; Cvacka J; Streinz L; Vrkocova P; Doubsky J; Simonova H; Felt L; Svoboda V; |
| Address: | "Department of Natural Products, Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Prague. koutek@uochb.cas.cz" |
| DOI: | 10.1016/s0021-9673(01)00965-7 |
| ISSN/ISBN: | 0021-9673 (Print) 0021-9673 (Linking) |
| Abstract: | "Validity of five models suggested for expressing the relationship between vapour pressures and GC retention times measured on a non-polar capillary column were tested on a common set of compounds [five homologous series of the type H-(CH2)n-Y, where Y denotes Cl, Br, CHO, OCOCH3 and COOCH3, and n varies from 6 to 14]. Standard methods of statistical analysis, as well as vapour pressure values obtained independently from direct vapour pressure measurements were used as validity criteria. For the 40-compound data set examined, the methods provided vapour pressures agreeing within 9.2-24.7% (average absolute percent error) with direct experimental data" |
| Keywords: | "Air Pressure Alkanes/chemistry Chromatography, Gas/*methods Pressure Reference Values Temperature Volatilization;" |
| Notes: | "MedlineKoutek, B Cvacka, J Streinz, L Vrkocova, P Doubsky, J Simonova, H Felt, L Svoboda, V eng Comparative Study Research Support, Non-U.S. Gov't Netherlands 2001/08/21 J Chromatogr A. 2001 Jul 20; 923(1-2):137-52. doi: 10.1016/s0021-9673(01)00965-7" |
