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Talanta

Title:		Determination of volatile organic compounds in eucalyptus fast pyrolysis bio-oil by full evaporation headspace gas chromatography
Author(s):		Kosinski Lima N; Romualdo Lopes A; Gimenes Guerrero P; Itsuo Yamamoto C; Augusto Hansel F;
Address:		"Departamento de Quimica e Biologia, Universidade Tecnologica Federal do Parana, Curitiba 81280 340, PR, Brazil. Laboratorio de Analises de Combustiveis Automotivos (Lacaut), Universidade Federal do Parana, Curitiba 81531-980, PR, Brazil. Embrapa Florestas, Estrada da Ribeira, km 111, C.P. 319, Guaraituba, Colombo 88411 000, PR, Brazil"
Journal Title:		Talanta
Year:		2018
Volume:		20170803
Issue:
Page Number:		47 - 51
DOI:		10.1016/j.talanta.2017.08.008
ISSN/ISBN:		1873-3573 (Electronic) 0039-9140 (Linking)
Abstract:		"This paper reports a full evaporation (FE) headspace gas chromatographic (HS-GC) method for the determination of the volatile organic compounds (VOCs) in bio-oil (i.e. methanol, ethanol, acetone, acetic acid and furfural). The method uses a 4muL sample of bio-oil in a headspace vial (ca. 20mL). Complete evaporation of the compounds was achieved after seven minutes at 90 degrees C. The method showed good precision and accuracy for methanol, ethanol, acetone and acetic acid. The recovery of furfural was low (74.3%). The results showed that the protocol can be applied for the determination of methanol, ethanol, acetone and acetic acid in bio-oil. Detection limits ranged from 0.13 to 0.16mug. Acetic acid was the dominant analyte in the heavy bio-oil and light bio-oil analysis (113. 3 and 85.1microgmg(-1), respectively), followed by methanol, ethanol, and acetone. The polymerisation of furfural was suspected as the cause of its poor quantification"
Keywords:		"Acetates/analysis Acetone/analysis Chromatography, Gas/methods Ethanol/analysis *Eucalyptus Furaldehyde/analysis Methanol/analysis Plant Oils/*analysis Polyphenols/*analysis Volatile Organic Compounds/*analysis Biofuel Biomass Fid Wood;"
Notes:		"MedlineKosinski Lima, Nathalya Romualdo Lopes, Andre Gimenes Guerrero, Palimecio Jr Itsuo Yamamoto, Carlos Augusto Hansel, Fabricio eng Netherlands 2017/09/18 Talanta. 2018 Jan 1; 176:47-51. doi: 10.1016/j.talanta.2017.08.008. Epub 2017 Aug 3"