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Chem Soc Rev

Title:		The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere
Author(s):		Johnson D; Marston G;
Address:		"Department of Chemistry, University of Reading, PO Box 224, Whiteknights, Reading, UK RG6 6AD"
Journal Title:		Chem Soc Rev
Year:		2008
Volume:		20080305
Issue:		4
Page Number:		699 - 716
DOI:		10.1039/b704260b
ISSN/ISBN:		0306-0012 (Print) 0306-0012 (Linking)
Abstract:		"The gas-phase reactions of ozone with unsaturated hydrocarbons are significant sources of free radical species (including *OH) and particulate material in the Earth's atmosphere. In this tutorial review, the kinetics, products and mechanisms of these reactions are examined, starting with a discussion of the original mechanism proposed by Criegee and following with a summary presentation of the complex, free radical-mediated reactions of carbonyl oxide (Criegee) intermediates. The contribution of ozone-terpene reactions to the atmospheric burden of secondary organic aerosol material is also discussed from the viewpoint of the formation of non-volatile organic acid products from the complex chemistry of ozone with alpha-pinene. Throughout the article, currently accepted understanding is supported through the presentation of key experimental results, and areas of persistent or new uncertainty are highlighted"
Keywords:
Notes:		"PubMed-not-MEDLINEJohnson, David Marston, George eng England 2008/03/26 Chem Soc Rev. 2008 Apr; 37(4):699-716. doi: 10.1039/b704260b. Epub 2008 Mar 5"