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J Chem Ecol


Title:Hesperophylax occidentalis (Trichoptera: Limnephilidae): Electroantennogram structure-activity study of sex pheromone component 6-methylnonan-3-one
Author(s):Jewett DK; Brigham DL; Bjostad LB;
Address:"Department of Entomology, Colorado State University, 80523, Fort Collins, Colorado"
Journal Title:J Chem Ecol
Year:1996
Volume:22
Issue:1
Page Number:123 - 137
DOI: 10.1007/BF02040204
ISSN/ISBN:0098-0331 (Print) 0098-0331 (Linking)
Abstract:"Electroantennogram (EAG) analyses ofHesperophylax occidentalis male and female antennae were used to generate dose-response curves for synthetic, racemic 6-methylnonan-3-one and to demonstrate the chemical specificity of male antennal olfactory cells. Male antennae responded to 6-methylnonan-3-one, the main female pheromone component. Females also demonstrated a response to 6-methylnonan-3-one, but a smaller one than males. The chemical specificity of male antennal receptors was determined by comparing EAG activity of synthetic, racemic 6-methylnonan-3-one and a series of structural analogs. The three structural parameters considered, including keto position, chain length, and methyl-group position, were demonstrated to contribute significantly to the reception of synthetic, racemic 6-methylnonan-3-one by male antennae. For straight-chain nonanones with keto groups at different positions, nonan-3-one elicited the greatest EAG responses from male antennae. For straight-chain alkan-3-ones with different chain lengths, the EAG responses of male antennae to nonan-3-one and decan-3-one were the same, but greater than those to other chain lengths. For methyl-branched nonan-3-ones, 6-methylnonan-3-one elicited greater EAG responses from antennae than analogs with the methyl group at another position"
Keywords:
Notes:"PubMed-not-MEDLINEJewett, D K Brigham, D L Bjostad, L B eng 1996/01/01 J Chem Ecol. 1996 Jan; 22(1):123-37. doi: 10.1007/BF02040204"

 
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