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J Chem Ecol


Title:"Enantiospecific synthesis of (3S,6R)-3-hydroxy-1,7-dioxaspiro[5.5]undecane and its (4R)-4-hydroxy isomer [minor components of olive fruit fly (Dacus oleae) sex pheromone]"
Author(s):Izquierdo Cubero I; Plaza Lopez-Espinosa MT; Castillo RA;
Address:"Department of Organic Chemistry Faculty of Pharmacy, University of Granada, 18071, Granada, Spain"
Journal Title:J Chem Ecol
Year:1992
Volume:18
Issue:2
Page Number:115 - 125
DOI: 10.1007/BF00993747
ISSN/ISBN:0098-0331 (Print) 0098-0331 (Linking)
Abstract:"The synthesis of (3S,6R)-3-hydroxy-1,7-dioxaspiro[5.5]undecane (8) and its (4R)-4-hydroxy isomer (11) from (3R,4S,6R)-3,4-dihydroxy-1,7-dioxaspiro[5.5]undecane (1), obtained from D-fructose, has been accomplished by regioselective deoxygenation at C-4 and C-3, respectively, of the appropriately protected derivatives"
Keywords:
Notes:"PubMed-not-MEDLINEIzquierdo Cubero, I Plaza Lopez-Espinosa, M T Castillo, R A eng 1992/02/01 J Chem Ecol. 1992 Feb; 18(2):115-25. doi: 10.1007/BF00993747"

 
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