Title: | Chirality and bioactivity of the sex pheromone of Madeira mealybug (Hemiptera: Pseudococcidae) |
Author(s): | Ho HY; Ko CH; Cheng CC; Su YT; Pola S; |
Address: | "Institute of Cellular and Organismic Biology, Academia Sinica, Taipei 115, Taiwan, Republic of China. shine@gate.sinica.edu.tw" |
ISSN/ISBN: | 0022-0493 (Print) 0022-0493 (Linking) |
Abstract: | "Two compounds (trans-1R,3R-chrysanthemyl R-2-methylbutanoate and R-lavandulyl R-2-methylbutanoate) identified from aeration extracts of virgin female Madeira mealybug, Phenacoccus madeirensis Green (Hemiptera: Pseudococcidae), were synthesized and tested in field bioassays in northern Taiwan over a 1-mo period. In total, 1,492 male P. madeirensis were captured in sticky traps. Our results showed that 1 microg of synthetic trans-1R,3R-chrysanthemyl R-2-methylbutanoate released from a plastic tube dispenser was attractive to the mealybugs. Different stereoisomers of chrysanthemyl 2-methylbutanoate also were tested. The insect-produced stereoisomer was the most attractive of all the isomers tested, and the stereochemistry of the acid moiety proved to be more critical than that of the alcohol moiety. The minor component found in extracts, R-lavandulyl R-2-methylbutanoate, alone was not attractive to male Madeira mealybugs nor did it act synergistically or additively with the main component" |
Keywords: | Animals Butyrates/chemistry/pharmacology Female Hemiptera/*chemistry/*physiology Insect Control Male Sex Attractants/*chemistry/*pharmacology Stereoisomerism Taiwan Terpenes/chemistry/pharmacology; |
Notes: | "MedlineHo, Hsiao-Yung Ko, Chi-Hung Cheng, Chao-Chih Su, Yu-Ting Pola, Someshwar eng Research Support, Non-U.S. Gov't England 2011/07/09 J Econ Entomol. 2011 Jun; 104(3):823-6. doi: 10.1603/ec10374" |