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Materials (Basel)


Title:Novel Graphene-Based Materials as a Tool for Improving Long-Term Storage of Cultural Heritage
Author(s):Gorgolis G; Ziemann S; Kotsidi M; Paterakis G; Koutroumanis N; Tsakonas C; Anders M; Galiotis C;
Address:"Institute of Chemical Engineering Sciences, Foundation of Research and Technology-Hellas (FORTH/ICE-HT), Stadiou Street, Platani, 26504 Patras, Greece. Department of Chemical Engineering, University of Patras, 26504 Patras, Greece. Zentrum fur Bucherhaltung GmbH (ZFB), Bucherstrasse 1, 04347 Leipzig, Germany"
Journal Title:Materials (Basel)
Year:2023
Volume:20230504
Issue:9
Page Number: -
DOI: 10.3390/ma16093528
ISSN/ISBN:1996-1944 (Print) 1996-1944 (Electronic) 1996-1944 (Linking)
Abstract:"The very serious problem of temperature and humidity regulation, especially for small and medium-sized museums, galleries, and private collections, can be mitigated by the introduction of novel materials that are easily applicable and of low cost. Within this study, archive boxes with innovative technology are proposed as 'smart' boxes that can be used for storage and transportation, in combination with a nanocomposite material consisting of polyvinyl alcohol (PVA) and graphene oxide (GO). The synthesis and characterization of the PVA/GO structure with SEM, Raman, AFM, XRD, Optical Microscopy, and profilometry are fully discussed. It is shown that the composite material can be integrated into the archive box either as a stand-alone film or attached onto fitting carriers, for example, those made of corrugated board. By applying the PVA/GO membrane this way, even with strong daily temperature fluctuations of DeltaT = +/-24.1 degrees C, strong external humidity fluctuations can be reduced by -87% inside the box. Furthermore, these humidity regulators were examined as Volatile Organic Compounds (VOCs) adsorbers since gas pollutants like formic acid, formaldehyde, acetic acid, and acetaldehyde are known to exist in museums and induce damages in the displayed or stored items. High rates of VOC adsorption have been measured, with the highest ones corresponding to formic acid (521% weight increase) and formaldehyde (223% weight increase)"
Keywords:cultural heritage graphene poly-vinyl alcohol temperature/humidity regulators;
Notes:"PubMed-not-MEDLINEGorgolis, George Ziemann, Steffen Kotsidi, Maria Paterakis, George Koutroumanis, Nikos Tsakonas, Christos Anders, Manfred Galiotis, Costas eng 101060941/GREENART/ 814496/APACHE/ Switzerland 2023/05/13 Materials (Basel). 2023 May 4; 16(9):3528. doi: 10.3390/ma16093528"

 
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