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Compound - geranial [(E)-3,7-Dimethyl-2,6-octadienal]

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(E)-3,7-Dimethyl-2,6-octadienal Formula:  C10H16O  CAS#:  141-27-5  MW:  152.23  [MS]  [ NMR ]  [ Kovats ]  [Behavioural function]  [Occurrence in flower]

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Reference(s) for synthesis of (E)-3,7-Dimethyl-2,6-octadienal [geranial] Ishihara, K., Kurihara, H., and Yamamoto, H. 1997. Bis(pentafluorophenyl)borinic acid as a highly effective Oppenauer oxidation catalyst for allylic and benzylic alcohols. J. Org. Chem. 62:5664-5665.   Kakiuchi, N., Nishimura, T., Inoue, M., and Uemura, S. 2001. Pd(II)-hydrotalcite-catalyzed selective oxidation of alcohols using molecular oxygen. Bull. Chem. Soc. Jpn. 74:165-172.   Matsushita, T., Ebitani, K., and Kaneda, K. 1999. Highly efficient oxidation of alcohols and aromatic compounds catalysed by the Ru-Co-Al hydrotalcite in the presence of molecular oxygen. Chem. Comm. 3:265-266.   Nakano, T., Ishii, Y., and Ogawa, M. 1987. Selective oxidation of alcohol function in allylic alcohols to alpha,ß-unsaturated carbonyl compounds catalyzed by zirconocene complexes. J. Org. Chem. 52:4855-4859.   Nasarow et al. 1959. Zh. Obshch. Khim. 29:3965-3966.   Sorg, G., Mengel, A., Jung, G., and Rademann, J. 2001. Oxidizing polymers: a polymer-supported, recyclable hypervalent iodine(V) reagent for the efficient conversion of alcohols, carbonyl compounds, and unsaturated carbamates in solution. Angew. Chem. Int. Ed. 40:4395-4397.