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Compound - E,E-2Sme6R8Sme-1,7-dioxaspiroundecane [(2S,6R,8S)-(E,E)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane]

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(2S,6R,8S)-(E,E)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane Formula:  C11H20O2  CAS#:    MW:  184.28  [MS]  [ NMR ]  [Behavioural function]

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Reference(s) for synthesis of (2S,6R,8S)-(E,E)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane [E,E-2Sme6R8Sme-1,7-dioxaspiroundecane] Enders, D., Dahmen, W., Dederichs, E., Gatzweiler, W., and Weuster, P. 1990. Synthesis of spiroacetal pheromones via metalated hydrazones. Synthesis. 11:1013-1019.   Giese, B., Bartmann, D., and Hasskerl, T. 1987. Synthesis of pheromones with acetal structures via C-C bond formation. Liebigs Ann. Chem. 427-430.   Kitching, W., Lewis, J.A., Perkins, M.V., Drew, R., Moore, C.J., Schurig, V., Koenig, W.A., and Francke, W. 1989. Chemistry of fruit flies. Composition of the rectal gland secretion of (male) Dacus cucumis (cucumber fly) and Dacus halfordiae. Characterization of (Z,Z)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane. J. Org. Chem. 54:3893-3902.   Pothier, N., Goldstein, S., and Deslongchamps, P. 1992. Cyclization of hydroxyenol ethers into spiroacetals. Evidence for the position of the transition state and its implication on the stereoelectronic effects in acetal formation. Helv. Chim. Acta. 75:604-620.