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Compound - 4S5R-sitophinone [(4S,5R)-5-Hydroxy-4-methylheptan-3-one]

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(4S,5R)-5-Hydroxy-4-methylheptan-3-one Formula:  C8H16O2  CAS#:  115014-45-4  MW:  144.21  [MS]  [ NMR ]  [ Kovats ]  [Behavioural function]

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Reference(s) for synthesis of (4S,5R)-5-Hydroxy-4-methylheptan-3-one [4S5R-sitophinone] Mori, K., Yoshimura, T., and Sugai, T. 1988. Synthesis of (4S,5R)-5-hydroxy-4-methyl-3-heptanone (sitophilure), the aggregation pheromone of Sitophilus oryzae and S. zeamais. Liebigs Ann. Chem. 899-902.   Oppolzer, W., and Rodriguez, I. 1993. Stereocontrolled syntheses of polysubstituted 2,3-dihydro-4H-pyran-4-ones by cyclocondensation of ß-acyloxy-ketones. Helv. Chim. Acta. 76:1282-1291.   Ramachandran, P.V., Zou, M.-F., and Brown, H.C. 2002. Efficient synthesis of B-iododialkyl- and B-alkyldiiodoboranes as their acetonitrile complexes: application for the enolboration-aldolization of ethyl ketones. Helv. Chim. Acta. 85:3027-3032.   Sato, F., Takeda, Y., Uchiyama, H., and Kobayashi, Y. 1984. Stereo- and regio-controlled aldol synthesis using relative 1,2-asymmetric induction. J. Chem. Soc. Chem. Comm. 16:1132-1134.